Honestly, I think you'll be perfectly fine running a 100shot on the stock 19#'s. Should provide enough fuel.
When going to a 100shot though, you may want to swap in plugs that are one step colder (AC Delco R44TS) and run some 93 octane.
I currently have a 75shot setup on my LB9. Wish I could feel the power a bit more though. I can't really feel when it kicks in, but I can sure notice my MPH higher at the end of a nice straightaway that I always test speed on. Used to get to about 85mph on the street which is just under a 1/4 (makes sense, my trap for 1/4 was 88). With the 75shot, I was able to hit roughly 92mph, which is roughly a 7mph gain, which means that nitrous must be giving me about another 75hp
I'm running stock (leaking) 19# injectors for now but will be swapping to 24# soon. However, I'll be running an LT1 intake and LT1 heads (flowed at 221/179 @ .500") with roughly a 10.2:1 CR, CC304 cam, and 1 3/4" headers. I'll also have an adjustable fuel pressure regulator and can burn my own chips.